GC-AED的CIC法定量測定神經(jīng)性毒劑研究

摘要： 用氣相色譜-原子發(fā)射光譜儀(GC-AED)對沙林(GB)、梭曼(GD)、維埃克斯(VX)進(jìn)行了分析,確定了氣相色譜的最佳分離條件;運(yùn)用GC-AED特有的化合物無關(guān)校正曲線法(CIC法),建立了GB、GD、VX CIC定量測定方法,計(jì)算出了各種方法的相對誤差,總結(jié)了CIC法的誤差規(guī)律;并利用建立的方法對實(shí)際染毒土壤樣品進(jìn)行定性定量測定,進(jìn)一步驗(yàn)證了結(jié)論的正確性。
Some systemic poisons such as Sarin(GB),Soman(GD),methylphonothioate(VX) have been studied by GC-AED.The best separated conditions were obtained.We established a quantitative determination method for GB,GD and VX by CIC.The relative error was calculated.The conclusion was proved by determination of poisoned pedotheque.